二噻英並二喹啉
| 二噻英並二喹啉 | |
|---|---|
| |
| IUPAC名 2,13-Dithia-10,21-diazapentacyclo[12.8.0.03,12.04,9.015,20]docosa-1(14),3(12),4,6,8,10,15,17,19,21-decaene | |
| 別名 | Thiochinathren |
| 識別 | |
| CAS號 | 50634-27-0 
|
| PubChem | 10870863 |
| ChemSpider | 9046144 |
| SMILES |
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| 性質 | |
| 化學式 | C18H10N2S2 |
| 摩爾質量 | 318.42 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
二噻英並二喹啉（[1,4]二噻英並[2,3-c:5,6-c']二喹啉）是一種有機化合物，化學式為C18H10N2S2。它的異構體[1,4]二噻英並[2,3-c:6,5-c']二喹啉（異二噻英並二喹啉）是已知的[1]，但它們的[1,2]二噻英異構體是未知的。
它可以喹啉和2-氯-3-甲硫基喹啉、硫為原料反應得到。[2]它可以被硝酸-硫酸氧化為二噻英並二喹啉-S-氧化物。[3]
參考文獻
[編輯]- ^ Andrzej Maślankiewicz, Krystian Pluta, Mirosław Wyszomirski, Adolf Gogoll, Maria J. Maślankiewicz. Complete assignment of the1H and13C NMR spectra of thioquinanthrene and isothioquinanthrene. Magnetic Resonance in Chemistry. 1998-01, 36 (1): 73–75 [2023-06-17]. ISSN 0749-1581. doi:10.1002/(SICI)1097-458X(199801)36:13.0.CO;2-Y （英語）.
- ^ Maslankiewicz, Andrzej. Sulfurization of azines. Part VII. Exhaustive sulfurization of quinoline. Polish Journal of Chemistry (1985), 59(5-6), 511-520.
- ^ Maslankiewicz, Maria J.; Glowiak, Tadeusz. Nitrothioquinanthrenes and their S-oxides. Heterocycles (2003), 60(6), 1387-1400.
拓展閱讀
[編輯]- Maslankiewicz, A.; Bebenek, E. Azinyl sulfides. Part LVII. The reaction of some dithiinodiquinolines with potassium methoxide as a source of 4-quinolinones with 3-sulfide function. Polish Journal of Chemistry, 1999. 73 (11): 1783-1789.